Ukrainian Journal of Physical Optics


2026 Volume 27, Issue 2


ISSN 1816-2002 (Online), ISSN 1609-1833 (Print)

IN-DEPTH NUMERICAL EVALUATION AND PERFORMANCE OPTIMIZATION OF CMTS PHOTODETECTOR

S. Yasin, Z. Abu Waar, S. Christopoulos and M. Moustafa


ABSTRACT

Photodetectors are essential elements in a wide range of technological fields, especially for advanced photosensing applications. This study presents a detailed numerical assessment and optimization of the performance of Copper Manganese Tin Sulfide (CMTS) layers, with particular focus on the absorber layer in a photodetector device. The investigation focuses on the influence of various design parameters, with an emphasis on maximizing the efficiency and functionality of the Fluorine-doped Tin Oxide (FTO)/CMTS/Au structure. A comprehensive numerical analysis of the physical properties of the CMTS absorber layer identifies, within the studied range, the optimal thickness, bandgap, doping density, and electron-hole mobility for enhanced photodetector performance at 1000 nm, 1.3 eV, 1×1014cm-3, and 28 cm2/Vs, respectively. Additionally, the influence of the incident light wavelength on photodetector behaviour is explored. The results indicate that the device performs optimally with an incident light wavelength of 800 nm. Under these optimized values and conditions, the photodetector achieves a responsivity of 0.56 A/W and a detectivity of 5.17×1013 Jones. These results demonstrate that the proposed device offers a promising pathway toward cost-effective, easily fabricated, and robust photodetectors, establishing it as a highly promising material for future photosensing technology.

Keywords: photodetector, copper-manganese-tin sulfide, responsivity, detectivity, solar cell capacitance simulator

UDC: 535.2

    1. Marouf, H., Abdel-Salam, N., El-Rabaie, E. S. M., Rashed, A. N. Z., & ElKhamisy, K. M. (2025). A Comprehensive Review Of Photodetectors: Materials, enhancement techniques, perspectives, and recent directions. Journal of Optics, 1-23.
      doi:10.1007/s12596-025-02779-4
    2. Chetia, A., Bera, J., Betal, A., & Sahu, S. (2022). A brief review on photodetector performance based on zero-dimensional and two-dimensional materials and their hybrid structures. Materials Today Communications, 30, 103224.
      doi:10.1016/j.mtcomm.2022.103224
    3. Abbas, K., Ji, P., Ullah, N., Shafique, S., Zhang, Z., Ameer, M. F., Qin, S., & Yang, S. (2024). Graphene photodetectors integrated with silicon and perovskite quantum dots. Microsystems & Nanoengineering, 10, 81.
      doi:10.1038/s41378-024-00722-4
    4. Ren, H., Chen, J.-D., Li, Y.-Q., & Tang, J.-X. (2021). Recent progress in organic photodetectors and their applications. Advanced Science, 8(1), 2002418.
      doi:10.1002/advs.202002418
    5. Jiao, Y., Lu, G., Feng, Y., Zhang, C., Wang, W., Wu, S., Chen, M., Ma, M., Li, W., & Yang, C. (2021). Towards high-sensitivity infrared detectors using Cu2CdxZn(1-x)SnSe4 thin films by SCAPS simulation. Solar Energy, 225, 375-381.
      doi:10.1016/j.solener.2021.07.044
    6. Wang, H., Sun, Y., Chen, J., Wang, F., Han, R., Zhang, C., Kong, J., Li, L., & Yang, J. (2022). A review of perovskite-based photodetectors and their applications. Nanomaterials, 12, 4390.
      doi:10.3390/nano12244390
    7. Chetia, A., Saikia, D., & Sahu, S. (2022). Design and optimization of the performance of CsPbI3-based vertical photodetectors using SCAPS simulation. Optik, 269, 169804.
      doi:10.1016/j.ijleo.2022.169804
    8. Zou, J., Zhang, S., & Tang, X. (2024). Recent advances in organic photodetectors. Photonics, 11(11), 1014.
      doi:10.3390/photonics11111014
    9. Yu, Y., Hu, Y., Yang, J., & Wei, Z. (2022). Recent advances in wide-spectrum photodetectors based on low-dimensional semiconductors. Materials Today Electronics, 2, 100013.
      doi:10.1016/j.mtelec.2022.100013
    10. Li, S., Zhang, Y., Yang, W., Liu, H., & Fang, X. (2020). 2D perovskite Sr2Nb3O10 for high-performance UV photodetectors. Advanced Materials, 32(7), 1905443.
      doi:10.1002/adma.201905443
    11. Kaifi, M., & Gupta, S. K. (2019). Simulation of perovskite-based solar cells and photodetectors using SCAPS software. International Journal of Engineering Research & Technology, 12(10), 1778-1786.
    12. Saidaminov, M. I., Adinolfi, V., Comin, R., Abdelhady, A. L., Peng, W., Dursun, I., Yuan, M., Hoogland, S., Sargent, E. H., & Bakr, O. M. (2015). Planar-integrated single-crystalline perovskite photodetectors. Nature Communications, 6, 8724.
      doi:10.1038/ncomms9724
    13. Li, G., Wang, Y., Huang, L., & Sun, W. (2022). Research progress of high-sensitivity perovskite photodetectors: Noise, structure, and materials. ACS Applied Electronic Materials, 4(4), 1485-1505.
      doi:10.1021/acsaelm.1c01349
    14. Geng, X., Wang, F., Tian, H., Feng, Q., et al. (2020). Ultrafast photodetectors by integrating perovskites directly on silicon wafers. ACS Nano, 14, 2860-2868.
      doi:10.1021/acsnano.9b06345
    15. Zhao, J., Zhao, L., Deng, Y., Xiao, X., Ni, Z., Xu, S., & Huang, J. (2020). Perovskite-filled membranes for flexible and large-area direct-conversion X-ray detector arrays. Nature Photonics, 14, 612-617.
      doi:10.1038/s41566-020-0678-x
    16. Dong, Y., Gu, Y., Zou, Y., Song, J., Xu, L., Li, J., Xue, J., Li, X., & Zeng, H. (2016). Improving all-inorganic perovskite photodetectors by preferred orientation and plasmonic effects. Small, 12, 5622-5632.
      doi:10.1002/smll.201602366
    17. Palchoudhury, S., Ramasamy, K., & Gupta, A. (2020). Multinary copper-based chalcogenide nanocrystal systems for device applications. Nanoscale Advances, 2, 3069-3082.
      doi:10.1039/D0NA00399A
    18. Cheng, X., Liu, J., Feng, J., Zhang, E., Wang, H., Liu, X., Rong, H., Xu, M., & Zhang, J. (2018). Metal@I2-II-IV-VI4 core-shell nanocrystals synthesized via aqueous cation exchange for efficient photoelectrochemical hydrogen generation. Journal of Materials Chemistry A, 6, 11898-11908.
      doi:10.1039/C8TA03070G
    19. Huang, S. H., Chen, C., Tay, Y. F., Chen, S., Tang, J., & Wong, L. (2022). Emerging chalcogenide thin films for solar energy harvesting devices. Chemical Reviews, 122(11), 10170-10265.
      doi:10.1021/acs.chemrev.1c00301
    20. Yilmaz, S., Basol, B. M., Atasoy, Y., Polat, I., Kucukomeroglu, T., & Bacaksiz, E. (2024). Enhancement of response speed of CIGS-based photodetectors by Te doping. Sensors and Actuators A: Physical, 377, 115691.
      doi:10.1016/j.sna.2024.115691
    21. Wu, H., Ma, C., Zhang, J., et al. (2021). High-performance photodetectors with ultrahigh photoswitching ratio and fast response speed in self-powered Cu2ZnSnS4/CdS PN heterojunctions. ACS Applied Electronic Materials, 3, 4135-4143.
      doi:10.1021/acsaelm.1c00597
    22. Chowdhury, T. A. (2024). SCAPS modeling of CMTS solar cells with ZrS2 buffer layers. Acta Physica Polonica A, 145(4), 215-224.
      doi:10.12693/APhysPolA.145.215
    23. Hassanien, A. S., & El Radaf, I. M. (2020). Optical characterization of quaternary Cu2MnSnS4 thin films synthesized by spray pyrolysis. Physica B: Condensed Matter, 585, 412110.
      doi:10.1016/j.physb.2020.412110
    24. Sarilmaz, A., Ozel, F., Karabulut, A., Orak, I., & Sahinkaya, M. A. (2020). Effects of temperature and frequency on the electrical characteristics of Cu2MnSnS4-based heterojunctions. Physica B: Condensed Matter, 580, 411821.
      doi:10.1016/j.physb.2019.411821
    25. Kukreti, S., Sapkota, D. J., Ramawat, S., & Dixit, A. (2022). Near-infrared photodetector performance of Cu2ZnSnS4 in MSM configuration: A theoretical study. Optik, 264, 169385.
      doi:10.1016/j.ijleo.2022.169385
    26. Roy, N. (2024). Investigating Cs2SnI6 as a promising material for high-performance self-powered broadband photodetection application. Journal of Physics and Chemistry of Solids, 203, 112730.
      doi:10.1016/j.jpcs.2025.112730
    27. Burgelman, M., Nollet, P., & Degrave, S. (2000). Modelling polycrystalline semiconductor solar cells. Thin Solid Films, 361-362, 527-532.
      doi:10.1016/S0040-6090(99)00825-1
    28. Hossain, M. K., Toki, G. F. I., Samajdar, D. P., et al. (2023). Coupled optoelectronic and photovoltaic analysis of lead-free CsSnI3 perovskite solar cells using DFT and SCAPS-1D simulations. ACS Omega, 8, 22466-22485.
      doi:10.1021/acsomega.3c00306
    29. Yasin, S., Christopoulos, S., Abu Waar, Z., & Moustafa, M. (2025). Numerical modeling and optimization of high-performance CsSnI3 perovskite photodetectors. Journal of Electronic Materials, 54, 5690-5700.
      doi:10.1007/s11664-025-11925-4
    30. Abu Waar, Z., Yasin, S., Christopoulos, S., & Moustafa, M. (2025). Exploring WS2 as a potential buffer layer for improved CFTS solar cell performance. Romanian Journal of Physics, 70, 612.
      doi:10.59277/RomJPhys.2025.70.612
    31. Yasin, S., Abu Waar, Z., Al Zoubi, T., & Moustafa, M. (2021). Optoelectronic simulation of a high-efficiency C2N-based solar cell via buffer layer optimization. Optical Materials, 119, 111364.
      doi:10.1016/j.optmat.2021.111364
    32. Makinudin, A., Al-Zuhairi, O., Anuar, A., Zainorin, M., Abu Bakar, A., DenBaars, S., & Supangat, A. (2021). Impact of crystallinity on the performance of semi-polar (11-22) GaN UV photodetectors. Materials Letters, 286, 129244.
      doi:10.1016/j.matlet.2020.129244
    33. Mohamad, W. F., Abou Hajar, A., & Saleh, A. N. (2006). Effects of oxide layers and metals on photoelectric and optical properties of Schottky barrier photodetectors. Renewable Energy, 31, 1493-1503.
      doi:10.1016/j.renene.2005.12.012
    34. Pansuriya, T., Malani, R., & Kheraj, V. (2022). Effect of buffer layer on CMTS-based thin-film solar cells using SCAPS-1D. Optical Materials, 126, 112150.
      doi:10.1016/j.optmat.2022.112150
    35. Isha, A., Kowsar, A., Kuddus, A., Hossain, M. K., Ali, M. H., Haque, M. D., & Rahman, M. F. (2023). High-efficiency Cu2MnSnS4 thin-film solar cells with SnS BSF and CdS ETL layers: A numerical simulation. Heliyon, 9(5), e15716.
      doi:10.1016/j.heliyon.2023.e15716
    36. Schukraft, G. E. M., Moss, B., Kafizas, A. G., & Petit, C. (2022). Effect of band bending in photoactive MOF-based heterojunctions. ACS Applied Materials & Interfaces, 14, 19342-19352.
      doi:10.1021/acsami.2c00335
    37. Ouslimane, T., Et-Taya, L., Elmaimouni, L., & Benami, A. (2021). Impact of absorber layer thickness, defect density, and operating temperature on MAPbI solar cells with ZnO ETL. Heliyon, 7(3), e06379.
      doi:10.1016/j.heliyon.2021.e06379
    38. Manzoor, G., Sharma, K. K., & Bharti, G. K. (2023). Modeling and simulation of heterojunction-based multilayer high-speed vertical CIGS photodetectors. In Proceedings of the International Conference for Advancement in Technology (ICONAT) (pp. 1-4).
      doi:10.1109/ICONAT57137.2023.10080239
    39. Xie, W., Du, C., Luo, Y., & Cao, S. (2025). Design and optimization of high responsivity and detectivity in lead-free tin-based perovskite photodetectors by numerical simulation. Journal of Physics and Chemistry of Solids, 207, 112919.
      doi:10.1016/j.jpcs.2025.112919
    40. Myers, S., Plis, E., Khoshakhlagh, A., Kim, H. S., Sharma, Y., Dawson, R., Krishna, S., & Gin, A. (2009). Effect of absorber doping on electrical and optical properties of nBn-based type-II InAs/GaSb strained-layer superlattice infrared detectors. Applied Physics Letters, 95, 121110.
      doi:10.1063/1.3230069
    41. Talebi, B., & Moradi, M. (2025). Role of MoS2 and MoSe2 thin films in the performance of new-generation CMTSe solar cells. Solar Energy, 292, 113449.
      doi:10.1016/j.solener.2025.113449
    42. Zhou, W., Ma, T., Tian, Y., Jiang, Y., & Yu, X. (2024). Dielectric-engineered graphene transistors for high-performance near-infrared photodetection. Science, 27(3), 109314.
      doi:10.1016/j.isci.2024.109314
    43. Su, L., Zuo, Y., & Xie, J. (2021). Scalable manufacture of vertical p-GaN/n-SnO2 heterostructures for self-powered ultraviolet photodetectors, solar cells, and dual-color LEDs. InfoMat, 3, 598-610.
      doi:10.1002/inf2.12127
    44. Tang, Y., Jin, P., Wang, Y., Li, D., et al. (2023). Enabling low-drift flexible perovskite photodetectors by electrical modulation for wearable health monitoring and weak-light imaging. Nature Communications, 14, 4961.
      doi:10.1038/s41467-023-40711-1
    45. Avdizhiyan, A. Y., Lavrov, S. D., Abdullaev, D. A., Shestakova, A. P., Kulyuk, L. L., & Mishina, E. D. (2021). Tunable spectral properties of photodetectors based on quaternary transition metal dichalcogenide alloys. IEEE Sensors Journal, 21(1), 325.
      doi:10.1109/JSEN.2020.3012876
    46. Shukla, R., Kumar, R. R., & Pandey, S. K. (2021). Theoretical study of charge carrier lifetime and recombination in eco-friendly perovskite solar cells. IEEE Transactions on Electron Devices, 68(7), 3446.
      doi:10.1109/TED.2021.3078063

    Фотодетектори є важливими елементами в широкому спектрі технологічних галузей, особливо для передових застосувань фоточутливості. Це дослідження представляє детальну числову оцінку та оптимізацію продуктивності шарів сульфіду міді-марганцю-олова (CMTS), зосереджуючись на функції поглинального шару у фотодетекторному пристрої. Дослідження зосереджене на аналізі впливу різних конструктивних параметрів, з акцентом на максимізацію ефективності та функціональності структури легованого фтором оксиду олова (FTO)/CMTS/Au. Комплексний чисельний аналіз фізичних властивостей поглинального шару CMTS дозволив визначити у досліджуваному діапазоні оптимальну товщину, ширину забороненої зони, концентрацію легування та електрон-діркову рухливість для підвищеної ефективності фотодетектора, які становлять відповідно 1000 нм, 1,3 еВ, 1×1014см-3 та 28 см2/с. Крім того, досліджено вплив довжини хвилі падаючого світла на поведінку фотодетектора. Результати показують, що пристрій демонструє оптимальну роботу при довжині хвилі падаючого випромінювання 800 нм. За цих оптимізованих значень та умов фотодетектор досягає чутливості 0,56 А/Вт та детективності 5,17×1013 Джонса. Отримані результати свідчать, що запропонований пристрій є перспективним для створення економічно ефективних, технологічно простих у виготовленні та надійних фотодетекторів, що робить його дуже перспективним матеріалом для майбутніх технологій фоточутливості.

    Ключові слова: фотодетектор, CMTS, чутливість, детективність, SCAPS


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